\u7532\u9178\u7532\u916f\uff0c\u522b\u540d\u8681\u9178\u7532\u916f\uff0c\u662f\u65e0\u8272\u6709\u9999\u5473\u7684\u6613\u6325\u53d1\u6db2\u4f53\u3002\u4e0e\u4e59\u9187\u6df7\u6eb6\uff0c\u6eb6\u4e8e\u7532\u9187\u3001\u3002\u5bb9\u6613\u6c34\u89e3\uff0c\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u7684\u6c34\u5206\u4e5f\u4f1a\u4f7f\u5176\u53d1\u751f\u6c34\u89e3\u3002\u5bf9\u547c\u5438\u9053\u3001\u773c\u3001\u9f3b\u548c\u4e0b\u547c\u5438\u9053\u6709\u8f83\u5f3a\u7684\u523a\u6fc0\u4f5c\u7528\uff0c\u53ef\u5f15\u8d77\u80f8\u90e8\u538b\u8feb\u611f\u3001\u547c\u5438\u56f0\u96be\u3002
\u78b3\u4e00\u5316\u5b66\u6781\u91cd\u8981\u7684\u4e2d\u95f4\u4f53\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u7528\u9014\uff0c\u53ef\u76f4\u63a5\u7528\u4f5c\u5904\u7406\u83f8\u8349\u3001\u5e72\u6c34\u679c\u3001\u8c37\u7269\u7b49\u7684\u70df\u85b0\u5242\u548c\u6740\u83cc\u5242\uff1b\u4e5f\u5e38\u7528\u4f5c\u785d\u5316\u7ea4\u7ef4\u7d20\u3001\u918b\u9178\u7ea4\u7ef4\u7d20\u7684\u6eb6\u5242\uff1b\u5728\u4e0a\uff0c\u5e38\u7528\u4f5c\u78fa\u9178\u7532\u57fa\u5627\u5576\u3001\u78fa\u9178\u7532\u6c27\u5627\u5576\u3001\u9547\u54b3\u5242\u7f8e\u6c99\u82ac\u7b49\u836f\u7269\u7684\u5408\u6210\u539f\u6599\u3002
\u4e2d\u6587\u540d\u7532\u9178\u7532\u916f\uff08MF\uff09\u82f1\u6587\u540dmethyl formate\u522b \u79f0\u8681\u9178\u7532\u916f\u5316\u5b66\u5f0fc\u5206\u5b50\u91cf60.05g\u00b7mol?1CAS\u767b\u5f55\u53f7107-31-3EINECS\u767b\u5f55\u53f7\u7194 \u70b9-100.4\u2103\u6cb8 \u70b932\u2103\u6c34\u6eb6\u6027\u6613\u6eb6\u4e8e\u6c34 (300 g\/L\uff0c20 \u00b0C)\u5bc6 \u5ea60.98 g\/cm3\u5916 \u89c2\u65e0\u8272\u6613\u6325\u53d1\u6db2\u4f53\u95ea \u70b9?32 \u00b0C\u5b89\u5168\u6027\u63cf\u8ff0\u6781\u6613\u71c3\uff0c\u6709\u5bb3\u5371\u9669\u6027\u7b26\u53f7\u6781\u6613\u71c3\uff08F+\uff09\uff0c\u6709\u5bb3\uff08Xn\uff09\u5371\u9669\u54c1\u8fd0\u8f93\u7f16\u53f7UN1243\u5916 \u89c2\u65e0\u8272\u6613\u6325\u53d1\u6db2\u4f53PubChem7865\u84b8\u6c7d\u538b644 hPa (20 \u00b0C)\u8b66\u793a\u672f\u8bedR\uff1a1R12, R20\/22, R36\/37\u5b89\u5168\u672f\u8bedS\uff1aS2, S9, S16, S24, S26, S33LD501500 mg\/kg
\u7ed3\u6784\u7f16\u8f91
\u540c\u5206\u5f02\u6784\u4f53\uff1a
\u4e59\u9178\uff0c\u53c8\u540d\u51b0\u918b\u9178\u3001\u51b0\u4e59\u9178\u3001\u918b\u9178
\u5206\u5b50\u5f0f\uff1aC2H4O2
\u5206\u5b50\u7ed3\u6784\u5f0f\uff1a
\u7532\u9178\u7532\u916f\u7684\u7ed3\u6784\u7b80\u5f0f\uff1bHCOOCH3\uff1b
\u7f16\u53f7\u7cfb\u7edf\u7f16\u8f91
CAS\u53f7\uff1a107-31-3
MDL\u53f7\uff1aMFCD00003291
EINECS\u53f7\uff1a203-481-7
RTECS\u53f7\uff1aLQ8925000
BRN\u53f7\uff1a1734623
\u7269\u6027\u6570\u636e\u7f16\u8f91
1.\u6027\u72b6\uff1a\u65e0\u8272\u6db2\u4f53\uff0c\u6709\u82b3\u9999\u6c14\u5473\u3002
2.\u7194\u70b9\uff08\u2103\uff09\uff1a-99.8
3.\u6cb8\u70b9\uff08\u2103\uff09\uff1a31.5
4.\u76f8\u5bf9\u5bc6\u5ea6\uff08\u6c34=1\uff09\uff1a0.98
5.\u76f8\u5bf9\u84b8\u6c14\u5bc6\u5ea6\uff08\u7a7a\u6c14=1\uff09\uff1a2.07
6.\u9971\u548c\u84b8\u6c14\u538b\uff08kPa\uff09\uff1a64\uff0820\u2103\uff09
7.\u71c3\u70e7\u70ed\uff08kJ\/mol\uff09\uff1a-973
8.\u4e34\u754c\u6e29\u5ea6\uff08\u2103\uff09\uff1a214
9.\u4e34\u754c\u538b\u529b\uff08MPa\uff09\uff1a6.00
10.\u8f9b\u9187\/\u6c34\u5206\u914d\u7cfb\u6570\uff1a0.03
11.\u95ea\u70b9\uff08\u2103\uff09\uff1a-19\uff08CC\uff09
12.\u5f15\u71c3\u6e29\u5ea6\uff08\u2103\uff09\uff1a449
13.\u4e0a\u9650\uff08%\uff09\uff1a20
14.\u4e0b\u9650\uff08%\uff09\uff1a5.9
15.\u6eb6\u89e3\u6027\uff1a\u6eb6\u4e8e\u6c34\u3001\u4e59\u9187\u3001\u3001\u7532\u9187\u3002
16.\u9ecf\u5ea6\uff08mPa\u00b7s,25oC\uff09\uff1a0.328
17.\u95ea\u70b9\uff08oC,\u95ed\u53e3\uff09\uff1a-26
18.\u95ea\u70b9\uff08oC,\u5f00\u53e3\uff09\uff1a-32
19.\u84b8\u53d1\u70ed\uff08KJ\/mol,31.5oC\uff09\uff1a28.26
20.\u7194\u5316\u70ed\uff08KJ\/mol\uff09\uff1a7.45
21.\u751f\u6210\u70ed\uff08KJ\/mol\uff09\uff1a378.47
22.\u6bd4\u70ed\u5bb9\uff08KJ\/(kg\u00b7K),15~20oC,\u5b9a\u538b\uff09\uff1a2.00
23.\u6cb8\u70b9\u4e0a\u5347\u5e38\u6570\uff0825oC\uff09\uff1a1.649
24.\u7535\u5bfc\u7387\uff08S\/m,20oC\uff09\uff1a3.6\u00d710-5
25.\u76f8\u5bf9\u5bc6\u5ea6\uff0820\u2103\uff0c4\u2103\uff09\uff1a0.9742
26.\u76f8\u5bf9\u5bc6\u5ea6\uff0825\u2103\uff0c4\u2103\uff09\uff1a0.9664
27.\u5e38\u6e29\u6298\u5c04\u7387\uff08n25\uff09\uff1a1.3415
28.\u4e34\u754c\u5bc6\u5ea6\uff1a0.349
29.\u4e34\u754c\u4f53\u79ef\uff1a172
30.\u4e34\u754c\u538b\u7f29\u56e0\u5b50\uff1a0.255
31.\u504f\u5fc3\u56e0\u5b50\uff1a0.254
32.\u6eb6\u5ea6\u53c2\u65700.5\uff1a20.503
\u5316\u5b66\u6027\u8d28\u7f16\u8f91
\u919b\u7684\u901a\u6027
\u53ef\u88ab\u6c27\u5316\uff0c\u4e5f\u53ef\u88ab\u8fd8\u539f\uff1b
\u7532\u9178\u7532\u916f\u542b\u6709\u919b\u57fa\uff0c\u80fd\u591f\u88ab\u50ac\u5316\u6c27\u5316\u4e3aCH3OCOOH
\u94f6\u6c28\u6eb6\u6db2\u53cd\u5e94
HCOOCH3+2Ag(NH3)2OH\u2192\u52a0\u70ed CH3OCOONH4+3NH3+2Ag + H2O
\u6590\u6797\u8bd5\u5242\u53cd\u5e94
\u7532\u9178\u7532\u916f\u56e0\u4e3a\u662f\u7532\u9178\u548c\u7532\u9187\u7684\u916f\uff0c\u7532\u9178\u90e8\u5206\u8fd8\u6709\u919b\u57fa\uff0c\u6240\u4ee5\u4f1a\u548c\u6c22\u6c27\u5316\u94dc\uff08\u65b0\u5236\uff09\u4ea7\u751f\u83f2\u6797\u8bd5\u5242\u53cd\u5e94\uff0c\u751f\u6210\u7816\u7ea2\u8272\u6c27\u5316\u4e9a\u94dc\u6c89\u6dc0
HCOOCH3+2Cu(OH)2=HOCOOCH3+Cu2O+2H2O
\u8fd8\u539f\u6027
\u7532\u9178\u4e2d\u7684\u7fa7\u57fa\u662f\u76f8\u5f53\u7684\u7a33\u5b9a\uff0c\u4e0d\u4f1a\u88ab\u8fd8\u539f\uff0c\u4f46\u662f\u7532\u9178\u8fd8\u6709\u201cHCO\uff0d\u201d\u90e8\u5206\u662f\u201c\u919b\u57fa\u201d\uff0c\u53ef\u4ee5\u52a0\u6c22\u53d8\u6210HOCH2\uff0d\uff0c\u800c\u53d8\u6210HOCH2OCH3\u3002\u919b\u57fa\u662f\u53ef\u4ee5\u5728Ni\u50ac\u5316\u7684\u60c5\u51b5\u4e0b\u88ab\u8fd8\u539f\u4e3a\u7f9f\u57fa\u7684\u3002
\u53cd\u5e94\u65b9\u7a0b\u5f0f\u4e3a\uff1a
HCOOH+2H2\u2014\u2014Ni\u50ac\u5316\u2192 CH3OH+H2O
\u53cd\u5e94\u539f\u7406\u662f\u7532\u9178\u4e2d\u7684\u919b\u57fa\u5148\u53d8\u6210\u7f9f\u57fa\uff0c\u7531\u4e8e\u4e00\u4e2a\u78b3\u539f\u5b50\u4e0a\u4e0d\u80fd\u540c\u65f6\u5b58\u5728\u4e24\u4e2a\u7f9f\u57fa\uff0c\u6240\u4ee5\u8fd9\u4e24\u4e2a\u7f9f\u57fa\u8131\u6c34\uff0c\u53c8\u53d8\u6210\u4e00\u4e2a\u919b\u57fa\u3002\u6b64\u919b\u57fa\u518d\u6b21\u88ab\u8fd8\u539f\uff0c\u6700\u7ec8\u53d8\u6210\u7532\u9187\u3002
\u916f\u7684\u901a\u6027\uff1a
\u6c34\u89e3\u53cd\u5e94
\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u53cd\u5e94\uff0c\u6216\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u7531\u65e0\u673a\u5f3a\u9178\u50ac\u5316\u53cd\u5e94
HCOOCH3+NaOH=HCOONa+CH3OH
\u71c3\u70e7\uff08\u5206\u89e3\uff09
\u6781\u6613\u71c3\uff0c\u5176\u84b8\u6c14\u4e0e\u7a7a\u6c14\u53ef\u5f62\u6210\u6027\u6df7\u5408\u7269\u3002\u9047\u660e\u706b\u3001\u9ad8\u70ed\u6216\u4e0e\u6c27\u5316\u5242\u63a5\u89e6\uff0c\u6709\u5f15\u8d77\u71c3\u70e7\u7684\u5371\u9669\u3002\u5728\u706b\u573a\u4e2d\uff0c\u53d7\u70ed\u7684\u5bb9\u5668\u6709\u5371\u9669\u3002\u5176\u84b8\u6c14\u6bd4\u7a7a\u6c14\u91cd\uff0c\u80fd\u5728\u8f83\u4f4e\u5904\u6269\u6563\u5230\u76f8\u5f53\u8fdc\u7684\u5730\u65b9\uff0c\u9047\u660e\u706b\u4f1a\u5f15\u7740\u56de\u71c3\u3002
\u71c3\u70e7(\u5206\u89e3)\u751f\u6210\u4e00\u6c27\u5316\u78b3\u3001\u4e8c\u6c27\u5316\u78b3\u3002
HCOOCH3+2O2=\u70b9\u71c3=2CO2+2H2O
\u6bd2\u7406\u5b66\u6570\u636e\u7f16\u8f91
1\u3001\u6025\u6027\u6bd2\u6027\uff1a\u5154\u5b50\u7ecf\u53e3LD50\uff1a1622mg\/kg\uff1b
2\u3001\u5176\u84b8\u6c14\u6709\u9ebb\u9189\u4f5c\u7528\u3002\u523a\u6fc0\u9f3b\u9ecf\u819c\uff0c\u5f15\u8d77\u5455\u5410\u3001\u56f0\u5026\uff0c\u4fb5\u8680\u80ba\u90e8\u3002\u5438\u5165\u53ef\u4f5c\u7528\u4e8e\u4e2d\u67a2\u795e\u7ecf\u7cfb\u7edf\u5f15\u8d77\u89c6\u89c9\u7b49\u969c\u788d\u3002\u6700\u9ad8\u5141\u8bb8\u6d53\u5ea6\u4e3a245.4\u6beb\u514b\u6bcf\u7acb\u65b9\u7c73\uff080.25mg\/L\u7a7a\u6c14\uff09\u3002\u5904\u57281%\u7684\u7532\u9178\u7532\u916f\u84b8\u6c14\u4e2d2.5\u5c0f\u65f6\uff0c\u62165%\u7684\u84b8\u6c14\u4e2d30\u5206\u949f\u65f6\uff0c\u5373\u6709\u81f4\u547d\u7684\u5371\u9669\u3002\u8c5a\u9f20\u5728\u7532\u9178\u7532\u916f128g\/mL\u7684\u73af\u5883\u4e2d\u63a5\u89e630\u5206\u949f\u81f4\u3002
3.\u6025\u6027\u6bd2\u6027
LD50\uff1a475mg\/kg\uff08\u5927\u9f20\u7ecf\u53e3\uff09\uff1b1622mg\/kg\uff08\u5154\u7ecf\u53e3\uff09
LC50\uff1a5200\u6beb\u514b\u6bcf\u7acb\u65b9\u7c73\uff08\u5927\u9f20\u5438\u5165\uff0c4h\uff09
4.\u4e9a\u6025\u6027\u4e0e\u6162\u6027\u6bd2\u6027 \u732b\u5438\u51652300\u6beb\u514b\u6bcf\u7acb\u65b9\u7c73\uff0c25h\uff0c1.5h\u540e\u8fd0\u52a8\u5931\u8c03\uff0c\u4fa7\u53672~3h\u5185\u4ea1\uff08\u80ba\u6c34\u80bf\uff09\u3002
\u751f\u6001\u5b66\u6570\u636e\u7f16\u8f91
1.\u751f\u6001\u6bd2\u6027
LC50\uff1a120mg\/L\uff0896h\uff09\uff08\u5706\u8179\u96c5\u7f57\u9c7c\uff0c\u9759\u6001\uff09
EC50\uff1a>500mg\/L\uff0824h\uff09\uff08\u6c34\u86a4\uff09\uff1b190mg\/L\uff0896h\uff09\uff08\u6805\u85fb\uff09
2.\u975e\u751f\u7269\u964d\u89e3\u6027 \u7a7a\u6c14\u4e2d\uff0c\u5f53\u7f9f\u57fa\u81ea\u7531\u57fa\u6d53\u5ea6\u4e3a \u4e2a\/\u7acb\u65b9\u5398\u7c733\u65f6\uff0c\u964d\u89e3\u534a\u8870\u671f\u4e3a71d\uff08\u7406\u8bba\uff09\u3002
\u5f53pH\u503c\u4e3a7\uff0c8\u65f6\uff0c\u6c34\u89e3\u534a\u8870\u671f\u5206\u522b\u4e3a5.1d\uff0c12d\uff08\u7406\u8bba\uff09\u3002
\u5206\u5b50\u7ed3\u6784\u6570\u636e\u7f16\u8f91
1\u3001\u6469\u5c14\u6298\u5c04\u7387\uff1a13.24
2\u3001\u6469\u5c14\u4f53\u79ef\uff1a65.2
3\u3001\u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a140.2
4\u3001\u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a21.3
5\u3001\u6781\u5316\u7387\uff1a5.25 [1]
\u8ba1\u7b97\u5316\u5b66\u6570\u636e\u7f16\u8f91
1.\u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09:\u65e0
2.\u6c22\u952e\u4f9b\u4f53\u6570\u91cf:0
3.\u6c22\u952e\u53d7\u4f53\u6570\u91cf:2
4.\u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf:1
5.\u4e92\u53d8\u5f02\u6784\u4f53\u6570\u91cf:\u65e0
6.\u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef26.3
7.\u91cd\u539f\u5b50\u6570\u91cf:4
8.\u8868\u9762\u7535\u8377:0
9.\u590d\u6742\u5ea6:18
10.\u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf:0
11.\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0
12.\u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0
13.\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0
14.\u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0
15.\u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf:1
\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027\u7f16\u8f91
1.\u7a33\u5b9a\u6027 \u7a33\u5b9a
2.\u7981\u914d\u7269 \u5f3a\u6c27\u5316\u5242\u3001\u78b1\u7c7b
3.\u805a\u5408\u5371\u5bb3 \u4e0d\u805a\u5408
\u8d2e\u5b58\u65b9\u6cd5\u7f16\u8f91
\u50a8\u5b58\u6ce8\u610f\u4e8b\u9879 \u50a8\u5b58\u4e8e\u9634\u51c9\u3001\u901a\u98ce\u7684\u5e93\u623f\u3002\u8fdc\u79bb\u706b\u79cd\u3001\u70ed\u6e90\u3002\u5e93\u6e29\u4e0d\u5b9c\u8d85\u8fc729\u2103\u3002\u4fdd\u6301\u5bb9\u5668\u5bc6\u5c01\u3002\u5e94\u4e0e\u6c27\u5316\u5242\u3001\u78b1\u7c7b\u5206\u5f00\u5b58\u653e\uff0c\u5207\u5fcc\u6df7\u50a8\u3002\u91c7\u7528\u9632\u7206\u578b\u7167\u660e\u3001\u901a\u98ce\u8bbe\u65bd\u3002\u7981\u6b62\u4f7f\u7528\u6613\u4ea7\u751f\u706b\u82b1\u7684\u673a\u68b0\u8bbe\u5907\u548c\u5de5\u5177\u3002\u50a8\u533a\u5e94\u5907\u6709\u6cc4\u6f0f\u5e94\u6025\u5904\u7406\u8bbe\u5907\u548c\u5408\u9002\u7684\u6536\u5bb9\u6750\u6599\u3002
\u5408\u6210\u65b9\u6cd5\u7f16\u8f91
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