\u57fa\u672c\u4fe1\u606f
(R)-(+)-\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80fa\uff0c\u5b66\u540d(R)-(+)-2-\u7532\u57fa-2-\u4e19\u70f7\u4e9a\u78fa\u9170\u80fa\uff0c\u4fd7\u79f0\u57c3\u5c14\u66fc\u4e9a\u78fa\u9170\u80fa\uff08Ellman’s sulfinamide\uff09\uff0c\u662f\u4e00\u79cd\u542b\u786b\u6709\u673a\u5316\u5408\u7269\uff0c\u5c5e\u4e8e\u4e9a\u78fa\u9178\u9170\u80fa\u7c7b\u5316\u5408\u7269\u3002\u5176CAS\u53f7\u4e3a196929-78-9\uff0c\u5206\u5b50\u5f0f\u4e3aC4H11NOS\uff0c\u5206\u5b50\u91cf\u4e3a121.2\u3002
\u7269\u7406\u6027\u8d28
\u82f1\u6587\u5168\u79f0\uff1a\u00ae-(+)-2-Methyl-2-propanesulfinamide
EINECS\u7f16\u53f7\uff1a1806241-263-5
\u7194\u70b9\uff1a103-107\u00b0C(lit.)
\u6cb8\u70b9\uff1a220.0\u00b123.0\u00b0C(Predicted)
\u5bc6\u5ea6\uff1a0.903g\/mL at 25\u00b0C
\u6bd4\u65cb\u5149\u5ea6\uff1a4\u00ba(c=1\uff0cCHCl3+amylenes)
\u6298\u5c04\u7387\uff1a4\u00b0(C=1\uff0cCHCl3)
\u95ea\u70b9\uff1a-17\u2103
\u50a8\u5b58\u6761\u4ef6\uff1a2-8\u00b0C
\u6eb6\u89e3\u5ea6\uff1a\u6613\u6eb6\u4e8e\u6c2f\u4eff\u3001\u7532\u9187\u3001\u56db\u6c22\u544b\u5583\u3001\u4e8c\u6c2f\u7532\u70f7\u3001\u4e8c\u7532\u57fa\u4e9a\u781c\u548c\u5927\u591a\u6570\u6709\u673a\u6eb6\u5242
\u5316\u5b66\u6027\u8d28
\u9178\u5ea6\u7cfb\u6570(pKa)\uff1a10.11\u00b10.50(Predicted)
\u5f62\u6001\uff1a\u7c89\u672b
\u989c\u8272\uff1a\u767d\u8272\u3001\u6d45\u7c89\u8272\u3001\u6d45\u9ec4\u8272\u81f3\u68d5\u8272
\u65cb\u5149\u6027\uff1a[\u03b1]22\/D+1.0\u00b0\uff0cc=0.5% in chloroform
\u7a33\u5b9a\u6027\uff1a\u51b7\u85cf
\u5236\u5907\u65b9\u6cd5
(R)-(+)-\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80fa\u7684\u5236\u5907\u53ef\u4ee5\u901a\u8fc7\u591a\u79cd\u65b9\u6cd5\u5b9e\u73b0\uff1a
\u65b9\u6cd5\u4e00
\u5bf9\u6620\u7eaf\u7ea7\u7684(R)-(+)-\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80fa\u53ef\u4ee5\u7531\u5ec9\u4ef7\u7684\u53d4\u4e01\u57fa\u4e8c\u786b\u7ecf\u8fc7\u7acb\u4f53\u9009\u62e9\u6027\u6c27\u5316\u6210\u786b\u4ee3\u4e9a\u78fa\u9178\u916f\uff0c\u518d\u5229\u7528\u6c28\u57fa\u9502\u4f7f\u4e8c\u786b\u952e\u65ad\u88c2\u5f97\u5230\u3002
\u7b2c\u4e00\u6b65\u7acb\u4f53\u9009\u62e9\u6027\u6c27\u5316\u8fc7\u7a0b\u7528\u5230\u4e86\u4e59\u9170\u4e19\u916e\u6c27\u9492(IV)\u548c\u6709\u673a\u624b\u6027\u914d\u4f53\uff0c\u8be5\u6709\u673a\u624b\u6027\u914d\u4f53\u75313\uff0c5-\u4e8c\u53d4\u4e01\u57fa\u6c34\u6768\u919b\u4e0e\u5149\u8c31\u7eaf\u7684\u624b\u6027\u6c28\u57fa\u831a\u6ee1\u9187\u7f29\u5408\u5f97\u5230\u3002
\u65b9\u6cd5\u4e8c
\u7528\u53d4\u4e01\u57fa\u4e8c\u786b\u919a\u4e0e\u53cc\u6c27\u6c34\u8fdb\u884c\u9009\u62e9\u6027\u6c27\u5316\uff0c\u968f\u540e\u4e0e\u9170\u5316\u8bd5\u5242\u5f97\u5230\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u6c2f\u6216\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u6eb4\uff0c\u968f\u540e\u4e0e\u6c34\u5408\u80bc\u5f97\u5230\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80bc\uff0c\u518d\u4e0e\u9152\u77f3\u9178\u62c6\u5206\u5242\u8fdb\u884c\u62c6\u5206\u89e3\u79bb\uff0c\u950c\u918b\u9178\u88c2\u89e3\u540e\u5f97\u5230(R)-(+)-\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80fa\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"
\u57fa\u672c\u4fe1\u606f(R)-(+)-\u53d4\u4e01\u57fa\u4e9a\u78fa\u9170\u80fa\uff0c\u5b66\u540d(R)-(+)-2-\u7532\u57fa-2-\u4e19\u70f7\u4e9a\u78fa\u9170\u80fa\uff0c\u4fd7\u79f0\u57c3\u5c14\u66fc\u4e9a\u78fa\u9170\u80fa\uff08E […]<\/p>\n","protected":false},"author":2,"featured_media":1389,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-5820","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-product"],"_links":{"self":[{"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/posts\/5820","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=5820"}],"version-history":[{"count":1,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/posts\/5820\/revisions"}],"predecessor-version":[{"id":5821,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/posts\/5820\/revisions\/5821"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=\/wp\/v2\/media\/1389"}],"wp:attachment":[{"href":"https:\/\/www.sdccet.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=5820"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=5820"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.sdccet.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=5820"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}